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After ball-milling in water, the calcined powder of com-position A which has pure perovskite phase (Fig. 1) was changed to a combination of perovskite BaPbO3, BaCO3 and PbO2 as shown in Fig. 6(a). The decomposition of BaPbO3 results in the high resistivity of the corresponding sintered specimens. In addition, the resulting PbO2 phase Fig. 6.